BS ISO 18118:2015 pdf free

BS ISO 18118:2015 pdf free.Surface chemical analysis一Auger electron spectroscopy and X-ray photoelectron spectroscopy
It is convenient in many quantitative applications of AES and XPS to utilize relative sensitivity factors (RSFs) for quantitative analyses. Three types of RSF have been used for this purpose: elemental relative sensitivity factors (ERSFs)， atomic relative sensitivity factors (ARSFs), and average matrix relative sensitivity factors (AMRSFs). Formulae defining these three types of RSF are given in A.3 and the principles on which these formulae are based on are given in A.2.
While the ERSFs are the simplest and easiest to apply, they are the least accurate because no account is taken of matrix correction factors (as described in A.3). The matrix correction factors for AES can vary between 0,1 and 8[1] while they can vary between 0,3 and 3[2] for XPS. The ARSFs are more accurate than ERSFs in that they take account of differences in atomic densities, generally the largest single matrix correction. The AMRSFs are the most reliable RSFs in that there is almost complete correction of matrix effects. It is recommended that ERSFs be used only for semi-quantitative analyses (that is, rough estimates of composition) and that ARSFs or preferably, AMRSFs be used for quantitative analyses. For the latter applications, ARSFs shall be used only in situations for which it is not possible to make use of AMRSFs (for example, measurements involving Auger electrons or photoelectrons at energies for which inelastic mean free paths cannot be reliably determined).
In analytical applications of AES and XPS, it is essential that Auger-electron and photoelectron intensities be measured using exactly the same procedure as that used for measurement of the RSFs.For some applications of AES (e.g. sputter depth profiles), it is convenient to use peak-to-peak heights of Auger-electron signals in the differential mode as measures of Auger-electron intensities. For other applications of AES (e.g. scanning Auger microscopy), the Auger-electron intensity can be determined from the difference between the intensity at a peak maximum in the direct spectrum and the intensity of a nearby background signal. Finally, for many applications in XPS and for some applications of AES,areas of peaks in direct spectra are used as measures of photoelectron or Auger-electron intensities.BS ISO 18118 pdf free download.